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1 article(s) from Ghosh, Soumen

A survey of chiral hypervalent iodine reagents in asymmetric synthesis

Soumen Ghosh,
Suman Pradhan and
Indranil Chatterjee

Beilstein J. Org. Chem. 2018, 14, 1244–1262, doi:10.3762/bjoc.14.107

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Graphical Abstract

Scheme 1: An overview of different chiral iodine reagents or precursors thereof.

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Scheme 2: Asymmetric oxidation of sulfides by chiral hypervalent iodine reagents.

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Scheme 3: Oxidative dearomatization of naphthol derivatives by Kita et al.

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Scheme 4: [4 + 2] Diels–Alder dimerization reported by Birman et al.

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Scheme 5: m-CPBA guided catalytic oxidative naphthol dearomatization.

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Scheme 6: Oxidative dearomatization of phenolic derivatives by Ishihara et al.

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Scheme 7: Oxidative spirocyclization applying precatalyst 11 developed by Ciufolini et al.

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Scheme 8: Asymmetric hydroxylative dearomatization.

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Scheme 9: Enantioselective oxylactonization reported by Fujita et al.

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Scheme 10: Dioxytosylation of styrene (47) by Wirth et al.

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Scheme 11: Oxyarylation and aminoarylation of alkenes.

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Scheme 12: Asymmetric diamination of alkenes.

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Scheme 13: Stereoselective oxyamination of alkenes reported by Wirth et al.

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Scheme 14: Enantioselective and regioselective aminofluorination by Nevado et al.

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Scheme 15: Fluorinated difunctionalization reported by Jacobsen et al.

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Scheme 16: Aryl rearrangement reported by Wirth et al.

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Scheme 17: α-Arylation of β-ketoesters.

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Scheme 18: Asymmetric α-oxytosylation of carbonyls.

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Scheme 19: Asymmetric α-oxygenation and α-amination of carbonyls reported by Wirth et al.

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Scheme 20: Asymmetric α-functionalization of ketophenols using chiral quaternary ammonium (hypo)iodite salt re...

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Scheme 21: Oxidative Intramolecular coupling by Gong et al.

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Scheme 22: α-Sulfonyl and α-phosphoryl oxylation of ketones reported by Masson et al.

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Scheme 23: α-Fluorination of β-keto esters.

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Scheme 24: Alkynylation of β-ketoesters and amides catalyzed by phase-transfer catalyst.

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Scheme 25: Alkynylation of β-ketoesters and dearomative alkynylation of phenols.

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Review

Published 30 May 2018

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